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Fluorous mixture synthesis of asymmetric dendrimers.

ABSTRACT: A divergent fluorous mixture synthesis (FMS) of asymmetric fluorinated dendrimers has been developed. Four generations of fluorinated dendrimers with the same fluorinated moiety were prepared with high efficiency, yield, and purity. Comparison of the physicochemical properties of these dendrimers provided valuable information for their application and future optimization. This strategy has not only provided a practical method for the synthesis and purification of dendrimers, but also established the possibility of utilizing the same fluorinated moiety for FMS.

SUBMITTER: Jiang ZX 

PROVIDER: S-EPMC2882623 | biostudies-literature | 2010 Mar

REPOSITORIES: biostudies-literature

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Fluorous mixture synthesis of asymmetric dendrimers.

Jiang Zhong-Xing ZX   Yu Yihua Bruce YB  

The Journal of organic chemistry 20100301 6

A divergent fluorous mixture synthesis (FMS) of asymmetric fluorinated dendrimers has been developed. Four generations of fluorinated dendrimers with the same fluorinated moiety were prepared with high efficiency, yield, and purity. Comparison of the physicochemical properties of these dendrimers provided valuable information for their application and future optimization. This strategy has not only provided a practical method for the synthesis and purification of dendrimers, but also established  ...[more]

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