Imidazolium cation supported solution-phase assembly of homolinear alpha(1-->6)-linked octamannoside: an efficient alternate approach for oligosaccharide synthesis.

ABSTRACT: An efficient, simple convergent assembly of a homolinear alpha(1-->6)-linked octamannosyl thioglycoside was obtained starting from imidazolium cation-tagged mannosyl fluoride and thiomannoside using block couplings. During chain elongation glycosylation reactions no column chromatographic purifications were used.

SUBMITTER: Yerneni CK 

PROVIDER: S-EPMC2888776 | biostudies-literature | 2009 Aug

REPOSITORIES: biostudies-literature