Synthesis of [(DPPNCH2CH2)3N]3- molybdenum complexes (DPP = 3,5-(2,5-Diisopropylpyrrolyl)2C6H3) and studies relevant to catalytic reduction of dinitrogen.

ABSTRACT: Molybdenum complexes that contain a new TREN-based ligand [(3,5-(2,5-diisopropyl-pyrrolyl)(2)C(6)H(3)NCH(2)CH(2))(3)N](3-) ([DPPN(3)N](3-)) that are relevant to the catalytic reduction of dinitrogen have been prepared. They are [Bu(4)N]{[DPPN(3)N]MoN(2)}, [DPPN(3)N]MoN(2), [DPPN(3)N]MoN=NH, {[DPPN(3)N]MoN=NH(2)}[BAr(f)(4)], [DPPN(3)N]Mo[triple bond]N, {[DPPN(3)N]Mo[triple bond]NH}[BAr(f)(4)], and {[DPPN(3)N]MoNH(3)}[BAr(f)(4)]. NMR and IR data for [Bu(4)N]{[DPPN(3)N]MoN(2)} and [DPPN(3)N]MoN(2) are close to those reported for the analogous [HIPTN(3)N](3-) compounds (HIPT = hexaisopropylterphenyl), which suggests that the degree of reduction of dinitrogen is virtually identical in the two systems. However, X-ray studies and several exchange studies support the conclusion that the apical poc

SUBMITTER: Reithofer MR 

PROVIDER: S-EPMC2895807 | biostudies-literature | 2010 Jun

REPOSITORIES: biostudies-literature