Ultrafast Time-resolved Absorption Spectroscopy of Geometric Isomers of Xanthophylls.

ABSTRACT: This paper presents an ultrafast optical spectroscopic investigation of the excited state energies, lifetimes and spectra of specific geometric isomers of neoxanthin, violaxanthin, lutein, and zeaxanthin. All-trans- and 15,15'-cis-beta-carotene were also examined. The spectroscopy was done on molecules purified by HPLC frozen immediately to inhibit isomerization. The spectra were taken at 77 K to maintain the configurations and to provide better spectral resolution than seen at room temperature. The kinetics reveal that for all of the molecules except neoxanthin, the S(1) state lifetime of the cis-isomers is shorter than that of the all-trans isomers. The S(1) excited state energies of all the isomers were determined by recording S(1) --> S(2) transient absorption spectra. The results obta

SUBMITTER: Niedzwiedzki DM 

PROVIDER: S-EPMC2913875 | biostudies-literature | 2010 Jul

REPOSITORIES: biostudies-literature