Redetermination of dicerium(III) tris-(sulfate) tetra-hydrate.

ABSTRACT: Ce(2)(SO(4))(3)(H(2)O)(4) was obtained hydro-thermally from an aqueous solution of cerium(III) oxide, trimethyl-amine and sulfuric acid. The precision of the structure determination has been significantly improved compared with the previous result [Dereigne (1972 ▶). Bull. Soc. Fr. Mineral. Cristallogr.95, 269-280]. The coordination about the two Ce atoms is achieved by seven and six bridging O atoms from sulfate anions. Each S atom makes four S-O-Ce linkages through bridging O atoms. The coordination sphere of each Ce is completed by two water molecules, which act as terminal ligands.

SUBMITTER: Xu X 

PROVIDER: S-EPMC2914879 | biostudies-literature | 2007 Dec

REPOSITORIES: biostudies-literature