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NaFe(TeO(3))(2).


ABSTRACT: The hydro-thermally prepared title compound, sodium iron(III) bis-[trioxotellurate(IV)], is isotypic with its Ga(III) analogue and consists of corrugated layers with an overall composition of [FeTe(2)O(6)](-) together with Na(+) cations. The layers extend parallel to (001) and are made up of [Fe(2)O(10)] edge-shared octa-hedral dimers and TeO(3) trigonal pyramids sharing vertices. The Na(+) cations are located in the cavities of this arrangement and link adjacent [FeTe(2)O(6)](-) layers via distorted [NaO(8)] polyhedra.

SUBMITTER: Weil M 

PROVIDER: S-EPMC2914881 | biostudies-literature | 2007 Dec

REPOSITORIES: biostudies-literature

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NaFe(TeO(3))(2).

Weil Matthias M   Stöger Berthold B  

Acta crystallographica. Section E, Structure reports online 20071206 Pt 1


The hydro-thermally prepared title compound, sodium iron(III) bis-[trioxotellurate(IV)], is isotypic with its Ga(III) analogue and consists of corrugated layers with an overall composition of [FeTe(2)O(6)](-) together with Na(+) cations. The layers extend parallel to (001) and are made up of [Fe(2)O(10)] edge-shared octa-hedral dimers and TeO(3) trigonal pyramids sharing vertices. The Na(+) cations are located in the cavities of this arrangement and link adjacent [FeTe(2)O(6)](-) layers via dist  ...[more]

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