Dicaesium tetra-chlorido-dioxido-plutonate(VI).

ABSTRACT: The anion of the title complex, Cs(2)[PuCl(4)O(2)], adopts a pseudo-octa-hedral geometry (2/m crystallographic site symmetry) with two plutonyl oxide ligands in axial sites and four chloride ligands occupying the equatorial plane. Charge balance is maintained by two caesium cations per tetra-chlorido-dioxido-plutonate(VI) anion. Principal bond lengths include Pu-O = 1.752 (3) Å and Pu-Cl = 2.6648 (8) Å.

SUBMITTER: Wilkerson MP 

PROVIDER: S-EPMC2914883 | biostudies-literature | 2007 Dec

REPOSITORIES: biostudies-literature