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Diazido-bis(2,2'-biimidazole)cobalt(II).

ABSTRACT: In the title compound, [Co(N(3))(2)(C(6)H(6)N(4))(2)], the Co(II) atom lies on a centre of inversion and is bonded to two azide ions and two bidentate 2,2'-biimidizole ligands, giving a slightly distorted octa-hedral CoN(6) coordination geometry. In the crystal structure, inter-molecular N-H⋯N hydrogen bonds exist between the 2,2'-biimidizole ligands and the azide ions, linking the complexes into sheets.

SUBMITTER: Li S

PROVIDER: S-EPMC2914954 | biostudies-literature | 2007 Dec

REPOSITORIES: biostudies-literature

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Diazido-bis(2,2'-biimidazole)cobalt(II).

Li Sheng S Wang Shou-Bin SB Zhang Fu-Li FL Tang Kun K

Acta crystallographica. Section E, Structure reports online 20071206 Pt 1

In the title compound, [Co(N(3))(2)(C(6)H(6)N(4))(2)], the Co(II) atom lies on a centre of inversion and is bonded to two azide ions and two bidentate 2,2'-biimidizole ligands, giving a slightly distorted octa-hedral CoN(6) coordination geometry. In the crystal structure, inter-molecular N-H⋯N hydrogen bonds exist between the 2,2'-biimidizole ligands and the azide ions, linking the complexes into sheets. ...[more]

PMID: 21200644

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