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Diaqua-bis(picolinato N-oxide-κO,O')zinc(II).

ABSTRACT: In the title compound, [Zn(C(6)H(4)NO(3))(2)(H(2)O)(2)], the Zn atom is located on a centre of inversion and shows a distorted octa-hedral coordination geometry. Two aqua ligands occupy the axial positions and four O atoms of the two chelating picolinic acid N-oxide ligands are located in the equatorial plane. Inter-molecular hydrogen bonds between aqua ligands and organic ligands link mol-ecules into a two-dimensional arrangement.

SUBMITTER: Li XB

PROVIDER: S-EPMC2915079 | biostudies-literature | 2007 Dec

REPOSITORIES: biostudies-literature

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Diaqua-bis(picolinato N-oxide-κO,O')zinc(II).

Li Xiu-Bing XB Shang Run-Ling RL Sun Bai-Wang BW

Acta crystallographica. Section E, Structure reports online 20071206 Pt 1

In the title compound, [Zn(C(6)H(4)NO(3))(2)(H(2)O)(2)], the Zn atom is located on a centre of inversion and shows a distorted octa-hedral coordination geometry. Two aqua ligands occupy the axial positions and four O atoms of the two chelating picolinic acid N-oxide ligands are located in the equatorial plane. Inter-molecular hydrogen bonds between aqua ligands and organic ligands link mol-ecules into a two-dimensional arrangement. ...[more]

PMID: 21200488

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