Unknown

Dataset Information

0

Dichlorido(3,5-dimethyl-1H-pyrazole)[(3,5-dimethyl-1H-pyrazol-1-yl)(o-tol-yl)methanone]palladium(II).

ABSTRACT: In the title compound, [PdCl(2)(C(5)H(8)N(2))(C(12)H(12)N(2)O)], the Pd atom adopts a slightly distorted trans-PdCl(2)N(2) square-planar arrangement. The different Pd-N bond lengths can be related to the the electron-withdrawing effect of the o-toluoyl group on the substituted pyrazole ligand. The complex crystallizes as centrosymmetric hydrogen-bonded dimers through N-H?Cl linkages.

SUBMITTER: Nelana SM 

PROVIDER: S-EPMC2915136 | biostudies-literature | 2007 Dec

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Dichlorido(3,5-dimethyl-1H-pyrazole)[(3,5-dimethyl-1H-pyrazol-1-yl)(o-tol-yl)methanone]palladium(II).

Nelana Simphiwe M SM   Kruger Gert J GJ   Darkwa James J  

Acta crystallographica. Section E, Structure reports online 20071218 Pt 1

In the title compound, [PdCl(2)(C(5)H(8)N(2))(C(12)H(12)N(2)O)], the Pd atom adopts a slightly distorted trans-PdCl(2)N(2) square-planar arrangement. The different Pd-N bond lengths can be related to the the electron-withdrawing effect of the o-toluoyl group on the substituted pyrazole ligand. The complex crystallizes as centrosymmetric hydrogen-bonded dimers through N-H⋯Cl linkages. ...[more]

Similar Datasets

Unknown Dichlorido(3,5-dimethyl-1H-pyrazole-κN)[hydro-tris-(3,5-dimethyl-1H-pyrazol-1-yl-κN)borato]chromium(III) tetra-hydro-furan mono-solvate.
| S-EPMC3051926 | biostudies-literature
Unknown (3,6-Dichloro-pyridin-2-yl)(3,5-dimethyl-1H-pyrazol-1-yl)methanone.
| S-EPMC2961666 | biostudies-literature
Unknown (3,5-Dimethyl-pyrazol-1-yl)[5-(3,5-dimethyl-pyrazol-1-ylcarbon-yl)-2-thien-yl]methanone.
| S-EPMC2970996 | biostudies-literature
Unknown cis-Dichlorido[2-(3,5-dimethyl-1H-pyrazol-1-yl-?N(2))ethanamine-?N]palladium(II) dichloro-methane monosolvate.
| S-EPMC3414152 | biostudies-literature
Unknown Dichlorido[2-(3,5-dimethyl-1H-pyrazol-1-yl-?N(2))quinoline-?N]zinc.
| S-EPMC3344321 | biostudies-literature
Unknown Dichlorido[2-(3,5-dimethyl-1H-pyrazol-1-yl-?N)ethanamine-?N]zinc(II).
| S-EPMC3253618 | biostudies-literature
Unknown (3,5-Dimethyl-1H-pyrazol-1-yl){3-[(3,5-dimethyl-1H-pyrazol-1-yl)carbon-yl]-5-methyl-indolizin-1-yl}methanone.
| S-EPMC3588476 | biostudies-other
Unknown Bis{4-[(3,5-dimethyl-1H-pyrazol-4-yl)selan-yl]-3,5-dimethyl-1H-pyrazol-2-ium} chloride monohydrate.
| S-EPMC3393332 | biostudies-literature
Unknown Chloridotris(3,5-dimethyl-1H-pyrazole-?N)(formato-?O)copper(II)-dichlorido-bis(3,5-dimethyl-1H-pyrazole-?N)copper(II) (2/1).
| S-EPMC3120383 | biostudies-literature
Unknown Dichlorido[2-(3,5-dimethyl-1H-pyrazol-1-yl-?N)-1,10-phenanthroline-?N,N']cadmium(II).
| S-EPMC2979538 | biostudies-literature