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{4,4'-Dimeth-oxy-2,2'-[ethyl-enedioxy-bis(nitrilo-methyl-idyne)]diphenolato}copper(II).

ABSTRACT: The title complex, [Cu(C(18)H(18)N(2)O(6))], was synthesized by the reaction of copper(II) acetate mono-hydrate with the ligand 4,4'-dimeth-oxy-2,2'-[ethyl-enedioxy-bis(nitrilo-methyl-idyne)]diphenol (H(2)L). The Cu atom is coordinated by two O atoms and two N atoms of the L(2-) unit. A bridged dimer is formed through inter-molecular Cu⋯O inter-actions [Cu⋯O = 1.9408 (15) Å], creating a distorted square-pyramidal geometry about the Cu atoms.

SUBMITTER: Sun YX

PROVIDER: S-EPMC2924182 | biostudies-literature | 2007 Dec

REPOSITORIES: biostudies-literature

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{4,4'-Dimeth-oxy-2,2'-[ethyl-enedioxy-bis(nitrilo-methyl-idyne)]diphenolato}copper(II).

Sun Yin-Xia YX Gao Su-Xia SX Shi Jun-Yan JY Dong Wen-Kui WK

Acta crystallographica. Section E, Structure reports online 20071221 Pt 1

The title complex, [Cu(C(18)H(18)N(2)O(6))], was synthesized by the reaction of copper(II) acetate mono-hydrate with the ligand 4,4'-dimeth-oxy-2,2'-[ethyl-enedioxy-bis(nitrilo-methyl-idyne)]diphenol (H(2)L). The Cu atom is coordinated by two O atoms and two N atoms of the L(2-) unit. A bridged dimer is formed through inter-molecular Cu⋯O inter-actions [Cu⋯O = 1.9408 (15) Å], creating a distorted square-pyramidal geometry about the Cu atoms. ...[more]

PMID: 21200572

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