Platinum(II)-catalyzed intermolecular hydroamination of monosubstituted allenes with secondary alkylamines.

ABSTRACT: A 1:1 mixture of (dppf)PtCl(2) and AgOTf (5 mol%) catalyzed the intermolecular hydroamination of monosubstituted allenes with secondary alkylamines at 80 degrees C to form allylic amines in good yield with selective formation of the E-diastereomer.

SUBMITTER: Toups KL 

PROVIDER: S-EPMC2924659 | biostudies-literature | 2010 Mar

REPOSITORIES: biostudies-literature