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Dataset Information

Catena-Poly[[(2,2'-bipyridine-κN,N')nickel(II)]-μ-oxalato-κO,O:O,O].


ABSTRACT: The title compound, [Ni(C(2)O(4))(C(10)H(8)N(2))](n), is isostructural with its Mn(II), Fe(II), Cu(II) and Zn(II) analogues. Each Ni(II) atom is chelated by two oxalate ligands and one 2,2'-bipyridine, forming a slightly distorted octa-hedral geometry. Oxlate acts as a bridge to link neighbouring pairs of Ni(II) cations, forming a one-dimensional wave-like chain. The crystal showed partial inversion twinning.

SUBMITTER: Li S 

PROVIDER: S-EPMC2959270 | biostudies-literature | 2008 Sep

REPOSITORIES: biostudies-literature