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(2-{[2-(4-Chlorophenoxy)-1-oxido-ethyl-idene-?O]hydrazono-methyl}-phenol-ato-?N,O)(1H-imidazole-?N)nickel(II).


ABSTRACT: In the title complex, [Ni(C(15)H(11)ClN(2)O(3))(C(3)H(4)N(2))], the Ni(II) ion is coordinated by a phenolate O, hydrazine N and carbonyl O atom from the hydrazone ligand and by an N atom from the imidazole mol-ecule, forming a distorted square-planar geometry. Inter-molecular N-H?N hydrogen bonds link neighboring molecules into extended chains parallel to [100].

SUBMITTER: Chen XH 

PROVIDER: S-EPMC2959330 | biostudies-literature | 2008 Sep

REPOSITORIES: biostudies-literature

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(2-{[2-(4-Chlorophenoxy)-1-oxido-ethyl-idene-κO]hydrazono-methyl}-phenol-ato-κN,O)(1H-imidazole-κN)nickel(II).

Chen Xiao-Hua XH  

Acta crystallographica. Section E, Structure reports online 20080906 Pt 10


In the title complex, [Ni(C(15)H(11)ClN(2)O(3))(C(3)H(4)N(2))], the Ni(II) ion is coordinated by a phenolate O, hydrazine N and carbonyl O atom from the hydrazone ligand and by an N atom from the imidazole mol-ecule, forming a distorted square-planar geometry. Inter-molecular N-H⋯N hydrogen bonds link neighboring molecules into extended chains parallel to [100]. ...[more]

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