Diethyl-enetriaminium hexa-fluorido-titanate(IV) fluoride.

ABSTRACT: The title compound, (C(6)H(21)N(4))[TiF(6)]F, was synthesized by the reaction of TiO(2), tris-(2-amino-ethyl)amine, HF and ethanol at 463 K in a microwave oven. The crystal structure consists of two crystallographically independent [TiF(6)](2-) anions, two fluoride anions and two triply-protonated tris-(2-amino-ethyl)-amine cations. The Ti atoms are coordinated by six F atoms within slightly distorted octa-hedra. The anions and cations are connected by inter-molecular N-H⋯F hydrogen bonds.

SUBMITTER: Lhoste J 

PROVIDER: S-EPMC2959685 | biostudies-literature | 2008 Oct

REPOSITORIES: biostudies-literature