Bis(acetyl-acetonato-κO,O')(methanol-κO)(thio-cyanato-κN)manganese(III).

ABSTRACT: In the title complex, [Mn(C(5)H(7)O(2))(2)(NCS)(CH(4)O)], the Mn(III) atom has a slightly distorted octa-hedral coordination formed by five O atoms and one N atom. The equatorial positions are occupied by four O atoms of two acetyl-acetonate ligands, while the axial positions are occupied by the N atom of the thio-cyanate anion and the O atom of the methanol mol-ecule. In the crystal structure, complex mol-ecules are linked by an inter-molecular O-H⋯S hydrogen bond, forming a chain running along [101].

SUBMITTER: Meng SM 

PROVIDER: S-EPMC2959789 | biostudies-literature | 2008 Oct

REPOSITORIES: biostudies-literature