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[μ-2,2,4,4,6,6-Hexakis(3,5-dimethyl-pyrazol-1-yl)-2λ,4λ,6λ-1,3,5,2,4,6-triaza-triphosphinine]bis-[bis-(nitrato- κO,O')cadmium(II)].

ABSTRACT: The complete title complex, [Cd(2)(NO(3))(4)(C(30)H(42)N(15)P(3))], is generated by crystallographic twofold symmetry, with one P and one N atom of the cyclo-triphosphazene ligand located on the rotation axis. The non-planar cyclo-triphosphazene ring accommodates two Cd ions, and only four out of six exocylcic pyrazolyl ligands are bound to the Cd metal atoms. Each of these two symmetry-related Cd atoms is coordinated by two bidentate nitrato ligands, two exocylic pyrazolyl N atoms, and one cyclo-triphosphazene N atom.

SUBMITTER: Yun SY

PROVIDER: S-EPMC2959902 | biostudies-literature | 2008 Nov

REPOSITORIES: biostudies-literature

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[μ-2,2,4,4,6,6-Hexakis(3,5-dimethyl-pyrazol-1-yl)-2λ,4λ,6λ-1,3,5,2,4,6-triaza-triphosphinine]bis-[bis-(nitrato- κO,O')cadmium(II)].

Yun Sung Yol SY Lee Soon W SW

Acta crystallographica. Section E, Structure reports online 20081108 Pt 12

The complete title complex, [Cd(2)(NO(3))(4)(C(30)H(42)N(15)P(3))], is generated by crystallographic twofold symmetry, with one P and one N atom of the cyclo-triphosphazene ligand located on the rotation axis. The non-planar cyclo-triphosphazene ring accommodates two Cd ions, and only four out of six exocylcic pyrazolyl ligands are bound to the Cd metal atoms. Each of these two symmetry-related Cd atoms is coordinated by two bidentate nitrato ligands, two exocylic pyrazolyl N atoms, and one cycl ...[more]

PMID: 21581131

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