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Poly[potassium-μ-2-[2-(carboxymethyl)phenyl]acetato].


ABSTRACT: In the title salt, [K(C(10)H(9)O(4))](n), the K(+) ions are coordinated by six O atoms from three different anions, and there is a cation-π inter-action at ca 3.14 Å. The 2-[2-(carboxymethyl)phenyl]acetate anions are stabilized by intramolecular O-H⋯O hydrogen bonds, and the K(+) cations are linked into one-dimensional coordination polymers running along the b axis; these are further inter-connected by weak C-H⋯O hydrogen bonds.

SUBMITTER: Garcia-Zarracino R 

PROVIDER: S-EPMC2960034 | biostudies-literature | 2008 Nov

REPOSITORIES: biostudies-literature

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Poly[potassium-μ-2-[2-(carboxymethyl)phenyl]acetato].

García-Zarracino Reyes R   Rangel-Marrón Marcela M   Tlahuext Hugo H   Höpfl Herbert H  

Acta crystallographica. Section E, Structure reports online 20081129 Pt 12


In the title salt, [K(C(10)H(9)O(4))](n), the K(+) ions are coordinated by six O atoms from three different anions, and there is a cation-π inter-action at ca 3.14 Å. The 2-[2-(carboxymethyl)phenyl]acetate anions are stabilized by intramolecular O-H⋯O hydrogen bonds, and the K(+) cations are linked into one-dimensional coordination polymers running along the b axis; these are further inter-connected by weak C-H⋯O hydrogen bonds. ...[more]

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