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Methyl-ene bis-(dithio-benzoate).

ABSTRACT: In the title compound, C(15)H(12)S(4), two phenyl-dithio-carboxyl-ate units are linked through a methyl-ene C atom on a twofold rotation axis. The central S-CH(2)-S angle of 116.9 (5)° is significantly larger than the ideal tetra-hedral value. The dihedral angle formed by the two phenyl rings is 68.2 (1)°. The refined Flack parameter of 0.2 (3) does not permit unambiguous determination of the absolute structure.

SUBMITTER: Liang YR

PROVIDER: S-EPMC2960133 | biostudies-literature | 2008 Nov

REPOSITORIES: biostudies-literature

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Methyl-ene bis-(dithio-benzoate).

Liang Yao-Ren YR Tong Hung-Chun HC Lo Yih-Hsing YH Lin Chia-Her CH Kuo Ting Shen TS

Acta crystallographica. Section E, Structure reports online 20081113 Pt 12

In the title compound, C(15)H(12)S(4), two phenyl-dithio-carboxyl-ate units are linked through a methyl-ene C atom on a twofold rotation axis. The central S-CH(2)-S angle of 116.9 (5)° is significantly larger than the ideal tetra-hedral value. The dihedral angle formed by the two phenyl rings is 68.2 (1)°. The refined Flack parameter of 0.2 (3) does not permit unambiguous determination of the absolute structure. ...[more]

PMID: 21581338

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