(Tetra-oxidoselenato-κO)tris-(thio-urea-κS)zinc(II).

ABSTRACT: The title structure, [Zn(SeO(4))(CH(4)N(2)S)(3)], is isomorphous with sulfatotris(thio-urea)zinc(II). In both structures, the Zn(2+) cation is coordinated in a tetra-hedral geometry. The corresponding intra-molecular distances are quite similar except for the Se-O and S-O distances. Although the hydrogen-bonding patterns are similar, there are some differences; in the title structure all the H atoms are involved in the hydrogen-bond pattern, in contrast to the situation in sulfatotris(thio-urea)zinc(II). No reproducible anomalies were detected by differential scanning calorimetry in the range 93-463 K until decomposition started at the higher temperature.

SUBMITTER: Krupkova R 

PROVIDER: S-EPMC2960388 | biostudies-literature | 2008 Jan

REPOSITORIES: biostudies-literature