Perchlorato[N,N,N',N'-tetra-kis(2-pyridyl-meth-yl)cyclo-hexane-1,2-diamine]manganese(II) perchlorate.

ABSTRACT: The asymmetric unit of the title compound, [Mn(ClO(4))(C(30)H(34)N(6))]ClO(4), consists of a cationic [Mn(ClO(4))(C(30)H(34)N(6))](+) complex and a perchlorate anion. In the complex, the Mn(2+) ion is seven-coordinated in an approximately penta-gonal-bipyramidal environment by six N atoms from the hexa-dentate N,N,N',N'-tetra-kis(2-pyridylmeth-yl)-cyclo-hexane-1,2-diamine (tpdach) ligand and one O atom from a perchlorate anion. The complex displays inter-molecular π-π inter-actions between adjacent pyridine rings (centroid-to-centroid distance 4.133 Å). Moreover, there are weak intra- and inter-molecular C-H⋯O hydrogen bonds. The Cl atom and two O atoms of the perchlorate are disordered, with a site-occupancy factor of 0.59 (2) for the major component.

SUBMITTER: Hwang IC 

PROVIDER: S-EPMC2960601 | biostudies-literature | 2008 Aug

REPOSITORIES: biostudies-literature