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Bis{4-[(Z)-(4-fluoro-benzyl-amino)(phenyl)-methyl-ene]-3-methyl-1-phenyl-1H-pyrazol-5(4H)-onato-κN,O}nickel(II).


ABSTRACT: The mol-ecule of the title compound, [Ni(C(24)H(19)FN(3)O)(2)], has twofold rotation symmetry. The Ni(II) ion is in a square-planar coordination geometry which is distorted towards tetra-hedral and is coordinated by two N atoms of imine and two O atoms of pyrazolone from two Schiff base 4-[(Z)-(4-fluoro-benzyl-amino)phenyl-methyl-ene]-3-methyl-1-phenyl-1H-pyrazol-5(4H)-onate ligands.

SUBMITTER: Zhang X 

PROVIDER: S-EPMC2961089 | biostudies-literature | 2008 Apr

REPOSITORIES: biostudies-literature

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Bis{4-[(Z)-(4-fluoro-benzyl-amino)(phenyl)-methyl-ene]-3-methyl-1-phenyl-1H-pyrazol-5(4H)-onato-κN,O}nickel(II).

Zhang Xin X   Zhang Guo-Ying GY   Chen Dan D   Song Yu-Jing YJ  

Acta crystallographica. Section E, Structure reports online 20080410 Pt 5


The mol-ecule of the title compound, [Ni(C(24)H(19)FN(3)O)(2)], has twofold rotation symmetry. The Ni(II) ion is in a square-planar coordination geometry which is distorted towards tetra-hedral and is coordinated by two N atoms of imine and two O atoms of pyrazolone from two Schiff base 4-[(Z)-(4-fluoro-benzyl-amino)phenyl-methyl-ene]-3-methyl-1-phenyl-1H-pyrazol-5(4H)-onate ligands. ...[more]

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