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(2,2'-Bipyridine-κN,N')iodido(pyrrol-idine-1-dithio-carboxyl-ato-κS,S')copper(II).

ABSTRACT: In the title compound, [Cu(C(5)H(8)NS(2))I(C(10)H(8)N(2))], the Cu(II) ion is coordinated by one iodide ion, two N atoms of the bipyridine ligand and two S atoms from the pyrrolidine-1-dithio-carboxyl-ate ligand in a distorted square-pyramidal environment.

SUBMITTER: Fan LQ

PROVIDER: S-EPMC2961148 | biostudies-literature | 2008 Apr

REPOSITORIES: biostudies-literature

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(2,2'-Bipyridine-κN,N')iodido(pyrrol-idine-1-dithio-carboxyl-ato-κS,S')copper(II).

Fan Le-Qing LQ Wu Ji-Huai JH

Acta crystallographica. Section E, Structure reports online 20080410 Pt 5

In the title compound, [Cu(C(5)H(8)NS(2))I(C(10)H(8)N(2))], the Cu(II) ion is coordinated by one iodide ion, two N atoms of the bipyridine ligand and two S atoms from the pyrrolidine-1-dithio-carboxyl-ate ligand in a distorted square-pyramidal environment. ...[more]

PMID: 21202189

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(2,2'-Bipyridine-κN,N')bis-(N-ethyl-N-methyl-dithio-carbamato-κS,S')zinc(II).

Project description:The complete mol-ecule of the title compound, [Zn(C(4)H(8)NS(2))(2)(C(10)H(8)N(2))], is generated by crystallographic twofold symmetry, with the Zn atom lying on the rotation axis; the axis also bis-ects the central C-C bond of the 2,2'-bipyridine mol-ecule. The metal atom is chelated by two S,S'-bidentate dithio-carbamate anions and the N,N'-bidentate heterocycle, resulting in a distorted cis-ZnN(2)S(4) octa-hedral geometry. The methyl and ethyl groups of the anion are statistically disordered.

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Project description:The copper(II) atom in the title compound, [Cu(C(5)H(10)NS(2))I(C(12)H(8)N(2))], is chelated by the N-heterocycle and the dithio-carbamate anion in a slightly distorted tetragonal coordination. The tetragonal-pyramidal coorination is completed by the iodine atom in the apical position. One ethyl group is disordered over two positions with site occupancies of 0.31 (2) and 0.69 (2).

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