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(μ-4-Methyl-benzene-thiol-ato-κS:S)bis-[carbon-yl(η-cyclo-penta-dien-yl)molybdenum(II)].

ABSTRACT: The asymmetric unit of the title compound, [Mo(2)(C(5)H(5))(2)(C(7)H(7)S)(2)(CO)(2)], consists of two half-mol-ecules, each molecule lying on a centre of symmetry. The thiol-ate groups function as bridges between the Mo(II) atoms, which adopt a quasi-octa-hedral geometry. In the octa-hedral environment the two ligating S atoms are in a cis arrangement.

SUBMITTER: Wong RC

PROVIDER: S-EPMC2961228 | biostudies-literature | 2008 Apr

REPOSITORIES: biostudies-literature

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(μ-4-Methyl-benzene-thiol-ato-κS:S)bis-[carbon-yl(η-cyclo-penta-dien-yl)molybdenum(II)].

Wong Richard Chee Seng RC Ooi Mei Lee ML Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20080423 Pt 5

The asymmetric unit of the title compound, [Mo(2)(C(5)H(5))(2)(C(7)H(7)S)(2)(CO)(2)], consists of two half-mol-ecules, each molecule lying on a centre of symmetry. The thiol-ate groups function as bridges between the Mo(II) atoms, which adopt a quasi-octa-hedral geometry. In the octa-hedral environment the two ligating S atoms are in a cis arrangement. ...[more]

PMID: 21202229

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