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1-(2-Methyl-benzo-yl)-3-m-tolyl-thio-urea.

ABSTRACT: The molecule of the title compound, C(16)H(16)N(2)OS, is not planar; the two aromatic rings are inclined to one another by 37.59 (9)°. There are intra-molecular hydrogen bonds between the benzoyl O atom and the H atom of the thio-amide N atom, and between the thio-urea S atom and the H atom of the tolyl group. These hydrogen bonds stabilize the mol-ecule in such a way that the thio-urea group adopts a trans-cis geometry. In the crystal structure, mol-ecules are linked by N-H⋯S inter-molecular hydrogen bonds, forming centrosymmetric dimers.

SUBMITTER: Yamin BM 

PROVIDER: S-EPMC2961788 | biostudies-literature | 2008 Jun

REPOSITORIES: biostudies-literature

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1-(2-Methyl-benzo-yl)-3-m-tolyl-thio-urea.

Yamin B M BM   Yousuf S S   Yusof M S M MS   Zakaria T N D T TN  

Acta crystallographica. Section E, Structure reports online 20080607 Pt 7

The molecule of the title compound, C(16)H(16)N(2)OS, is not planar; the two aromatic rings are inclined to one another by 37.59 (9)°. There are intra-molecular hydrogen bonds between the benzoyl O atom and the H atom of the thio-amide N atom, and between the thio-urea S atom and the H atom of the tolyl group. These hydrogen bonds stabilize the mol-ecule in such a way that the thio-urea group adopts a trans-cis geometry. In the crystal structure, mol-ecules are linked by N-H⋯S inter-molecular hy  ...[more]

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