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Zr(3)NiSb(7): a new anti-mony-enriched ZrSb(2) derivative.

ABSTRACT: Single crystals of trizirconium nickel hepta-anti-monide were synthesized from the constituent elements by arc-melting. The compound crystallizes in a unique structure type and belongs to the family of two-layer structures. All crystallographically unique atoms (3 × Zr, 1 × Ni and 7 × Sb) are located at sites with m symmetry. The structure contains 'Zr(2)Ni(2)Sb(5)' and 'Zr(4)Sb(9)' fragments and might be described as a new ZrSb(2) derivative with a high Sb content.

SUBMITTER: Romaka V 

PROVIDER: S-EPMC2961902 | biostudies-literature | 2008 Jul

REPOSITORIES: biostudies-literature

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Zr(3)NiSb(7): a new anti-mony-enriched ZrSb(2) derivative.

Romaka V V   Tkachuk A A   Romaka L L  

Acta crystallographica. Section E, Structure reports online 20080705 Pt 8

Single crystals of trizirconium nickel hepta-anti-monide were synthesized from the constituent elements by arc-melting. The compound crystallizes in a unique structure type and belongs to the family of two-layer structures. All crystallographically unique atoms (3 × Zr, 1 × Ni and 7 × Sb) are located at sites with m symmetry. The structure contains 'Zr(2)Ni(2)Sb(5)' and 'Zr(4)Sb(9)' fragments and might be described as a new ZrSb(2) derivative with a high Sb content. ...[more]