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(E)-1-Ferrocenyl-3-phenyl-prop-2-en-1-one.

ABSTRACT: The title compound, [Fe(C(5)H(5))(C(14)H(11)O)], exists as the E isomer, and the substituent is fully conjugated with the attached five-membered ring. In the ferrocene unit, the substituted cyclo-penta-dienyl ring (Cps) plane and unsubstituted cyclo-penta-dienyl ring (Cp) plane are almost parallel, and the C atoms in Cp and Cps are in an eclipsed conformation. In the crystal structure, mol-ecules are linked into C(5) chains via inter-molecular C-H⋯O hydrogen bonds, and neighbouring chains are assembled into sheets by inter-molecular C-H⋯π(arene) hydrogen bonds along the c axis.

SUBMITTER: Liu YH

PROVIDER: S-EPMC2961926 | biostudies-literature | 2008 Jul

REPOSITORIES: biostudies-literature

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(E)-1-Ferrocenyl-3-phenyl-prop-2-en-1-one.

Liu Yong-Hong YH Liu Jian-Feng JF Jian Pan-Ming PM Liu Xiao-Lan XL

Acta crystallographica. Section E, Structure reports online 20080705 Pt 8

The title compound, [Fe(C(5)H(5))(C(14)H(11)O)], exists as the E isomer, and the substituent is fully conjugated with the attached five-membered ring. In the ferrocene unit, the substituted cyclo-penta-dienyl ring (Cps) plane and unsubstituted cyclo-penta-dienyl ring (Cp) plane are almost parallel, and the C atoms in Cp and Cps are in an eclipsed conformation. In the crystal structure, mol-ecules are linked into C(5) chains via inter-molecular C-H⋯O hydrogen bonds, and neighbouring chains are as ...[more]

PMID: 21202997

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