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Diazido-bis{2-[3-(dimethyl-amino)propyl-imino-meth-yl]phenol}manganese(III) perchlorate.

ABSTRACT: The title compound, [Mn(N(3))(2)(C(12)H(18)N(2)O)(2)]ClO(4), was synthesized from manganese(III) acetate, sodium azide and 2-[3-(dimethyl-amino)propyl-imino-meth-yl]phenol by a hydro-thermal reaction. The Mn(III) ion is hexa-coordinated by two N and two O atoms from two phenolate ligands and two N atoms from two azide ligands. The Mn(III) cation lies on an inversion centre and, as a result, the asymmetric unit comprises one half-mol-ecule.

SUBMITTER: Yang GB

PROVIDER: S-EPMC2961989 | biostudies-literature | 2008 Jul

REPOSITORIES: biostudies-literature

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Diazido-bis{2-[3-(dimethyl-amino)propyl-imino-meth-yl]phenol}manganese(III) perchlorate.

Yang Gui-Bin GB Sun Zhen-Hai ZH

Acta crystallographica. Section E, Structure reports online 20080731 Pt 8

The title compound, [Mn(N(3))(2)(C(12)H(18)N(2)O)(2)]ClO(4), was synthesized from manganese(III) acetate, sodium azide and 2-[3-(dimethyl-amino)propyl-imino-meth-yl]phenol by a hydro-thermal reaction. The Mn(III) ion is hexa-coordinated by two N and two O atoms from two phenolate ligands and two N atoms from two azide ligands. The Mn(III) cation lies on an inversion centre and, as a result, the asymmetric unit comprises one half-mol-ecule. ...[more]

PMID: 21203059

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