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Dibromido{(E)-2-eth-oxy-6-[3-(methyl-ammonio)propyl-iminometh-yl]phenol-ato}zinc(II).

ABSTRACT: The title complex, [ZnBr(2)(C(13)H(20)N(2)O(2))], is a mononuclear zinc(II) compound derived from the zwitterionic form of the Schiff base (E)-2-eth-oxy-6-((3-(methyl-amino)propyl-imino)meth-yl)phenol. The Zn(II) atom is four-coordinated by the imine N and phenolate O atoms of the Schiff base ligand, and by two bromide ions, in a tetra-hedral coordination geometry. Adjacent mol-ecules are linked through inter-molecular N-H⋯O hydrogen bonds, forming chains running along the b axis.

SUBMITTER: Zhu XW

PROVIDER: S-EPMC2961999 | biostudies-literature | 2008 Jul

REPOSITORIES: biostudies-literature

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Dibromido{(E)-2-eth-oxy-6-[3-(methyl-ammonio)propyl-iminometh-yl]phenol-ato}zinc(II).

Zhu Xue-Wen XW Yang Xu-Zhao XZ

Acta crystallographica. Section E, Structure reports online 20080731 Pt 8

The title complex, [ZnBr(2)(C(13)H(20)N(2)O(2))], is a mononuclear zinc(II) compound derived from the zwitterionic form of the Schiff base (E)-2-eth-oxy-6-((3-(methyl-amino)propyl-imino)meth-yl)phenol. The Zn(II) atom is four-coordinated by the imine N and phenolate O atoms of the Schiff base ligand, and by two bromide ions, in a tetra-hedral coordination geometry. Adjacent mol-ecules are linked through inter-molecular N-H⋯O hydrogen bonds, forming chains running along the b axis. ...[more]

PMID: 21203069

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