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9-(2-Pyridylmeth-oxy)-1,10-phenanthrolin-1-ium perchlorate methanol solvate.

ABSTRACT: In the title organic salt, C(18)H(14)N(3)O(+)·ClO(4) (-)·CH(4)O, there is a ?-? stacking inter-action between neighbouring 1,10-phenanthroline rings and the relevant distances are 3.5453?(18)?Å for the centroid-centroid distance and 3.354?Å for the perpendicular distance. There is also a relatively close contact between a C-H bond and a symmetry-related pyridine ring. There are classical N-H?O and O-H?N hydrogen bonds and non-classical C-H?O hydrogen bonds involving the cation, methanol solvent mol-ecule and perchlorate anion.

SUBMITTER: Zhang SG 

PROVIDER: S-EPMC2962027 | biostudies-literature | 2008 Jul

REPOSITORIES: biostudies-literature

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9-(2-Pyridylmeth-oxy)-1,10-phenanthrolin-1-ium perchlorate methanol solvate.

Zhang Shi Guo SG   Hou Chao C  

Acta crystallographica. Section E, Structure reports online 20080709 Pt 8

In the title organic salt, C(18)H(14)N(3)O(+)·ClO(4) (-)·CH(4)O, there is a π-π stacking inter-action between neighbouring 1,10-phenanthroline rings and the relevant distances are 3.5453 (18) Å for the centroid-centroid distance and 3.354 Å for the perpendicular distance. There is also a relatively close contact between a C-H bond and a symmetry-related pyridine ring. There are classical N-H⋯O and O-H⋯N hydrogen bonds and non-classical C-H⋯O hydrogen bonds involving the cation, methanol solvent  ...[more]

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