Unknown

Dataset Information

0

5-Hydr-oxy-1-methyl-3,4-dihydro-2H-pyrrolium hydrogensulfate.

ABSTRACT: The title compound, C(5)H(10)NO(+)·HSO(4) (-), has been synthesized by reaction of 1-methyl-pyrrolidin-2-one with H(2)SO(4) in a 1:1 molar ratio. The substituted pyrrolium ring adopts an envelope conformation. The hydrogensulfate anions form infinite helical chains parallel to the a axis via strong O-H?O hydrogen bonds. The pyrrolium cations are pendant from the chains. These cations are the hydrogen donors in the strong O-H?O hydrogen bonds to the hydrogensulfates. In addition, there are weak C-H?O hydrogen bonds in the structure.

SUBMITTER: Fang YX 

PROVIDER: S-EPMC2962183 | biostudies-literature | 2008 Jul

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

5-Hydr-oxy-1-methyl-3,4-dihydro-2H-pyrrolium hydrogensulfate.

Fang Yan-Xiong YX   Huang Hua-Rong HR   Du Zhi-Yun ZY   Huang Bao-Hua BH   Zhang Kun K  

Acta crystallographica. Section E, Structure reports online 20080731 Pt 8

The title compound, C(5)H(10)NO(+)·HSO(4) (-), has been synthesized by reaction of 1-methyl-pyrrolidin-2-one with H(2)SO(4) in a 1:1 molar ratio. The substituted pyrrolium ring adopts an envelope conformation. The hydrogensulfate anions form infinite helical chains parallel to the a axis via strong O-H⋯O hydrogen bonds. The pyrrolium cations are pendant from the chains. These cations are the hydrogen donors in the strong O-H⋯O hydrogen bonds to the hydrogensulfates. In addition, there are weak C  ...[more]

Similar Datasets

Unknown Methyl 3-hydr-oxy-4-oxo-3,4-dihydro-2H-1,2-benzothia-zine-3-carboxyl-ate 1,1-dioxide monohydrate.
| S-EPMC2959447 | biostudies-literature
Unknown 2-Hydr-oxy-3,3-dimethyl-7-nitro-3,4-dihydro-isoquinolin-1(2H)-one.
| S-EPMC2961355 | biostudies-literature
Unknown 4-Hydr-oxy-2,2,6,6-tetra-methyl-piperidinium hydrogensulfate monohydrate.
| S-EPMC2960323 | biostudies-literature
Unknown 7-Meth-oxy-3,4-dihydro-naphthalen-1(2H)-one.
| S-EPMC3152045 | biostudies-literature
Unknown 2-Meth-oxy-3-[(3,4,5-trimethoxy-anilino)methyl-idene]-3,4-dihydro-2H-1-benzopyran-4-one.
| S-EPMC2980241 | biostudies-literature
Unknown N-(3,4-Dimethyl-phen-yl)-4-hydr-oxy-2-methyl-2H-1,2-benzothia-zine-3-carboxamide 1,1-dioxide.
| S-EPMC2968962 | biostudies-literature
Unknown (1E)-6-Meth-oxy-3,4-dihydro-naphthalen-1(2H)-one oxime.
| S-EPMC2983376 | biostudies-literature
Unknown 3-(2H-Benzotriazol-2-yl)-2-hydr-oxy-5-methyl-benzaldehyde.
| S-EPMC2984053 | biostudies-literature
Unknown 5,7-Dibromo-3-trifluoro-methyl-3,4-dihydro-acridin-1(2H)-one.
| S-EPMC3213499 | biostudies-literature
Unknown 8-Meth-oxy-3-methyl-3,4-di-hydro-2H-1,3-benzoxazine.
| S-EPMC3884293 | biostudies-literature