Dichlorido{[2-(diphenyl-phosphino)phenyl-imino-meth-yl]ferrocene-κN,P}palladium(II) dichloro-methane hemi-solvate.

ABSTRACT: There are two independent Pd(II) complex mol-ecules in the asymmetric unit of the title compound, [PdCl(2){Fe(C(5)H(5))(C(24)H(19)NP)}]·0.5CH(2)Cl(2). One ferrocenyl ring of one complex mol-ecule is disordered over two sites with half-occupancy for each component. Both Pd(II) cations adopt a distorted square-planar coordination geometry with a bidentate [2-(diphenyl-phosphino)phenyl-imino-meth-yl]ferrocene ligand and two chloride anions.

SUBMITTER: Liu H 

PROVIDER: S-EPMC2967851 | biostudies-literature | 2008 Dec

REPOSITORIES: biostudies-literature