Bis(μ-5-chloro-quinolin-8-olato)-κN,O:O;κO:N,O-bis-[(acetato-κO,O')lead(II)].

ABSTRACT: The mol-ecule of the title compound, [Pb(2)(C(9)H(5)ClNO)(2)(C(2)H(3)O(2))(2)], lies about a center of inversion. The Pb(II) atom is chelated by acetate and substituted quinolin-8-olate anions; the O atoms of the quinolin-8-olates also bridge to confer a five-coordinate status to each metal center. The geometry approximates a distorted Ψ-fac octa-hedron in which one of the sites is occupied by a stereochemically active lone pair.

SUBMITTER: Mohammadnezhad Sh G 

PROVIDER: S-EPMC2968633 | biostudies-literature | 2009 Feb

REPOSITORIES: biostudies-literature