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(SP-4-4)-[Hydrogen N-({2-[(2S)-1-benzyl-pyrrolidine-2-carboxamido]phen-yl}(phen-yl)methyl-ene)-l-glutamato(2-)]nickel(II).

ABSTRACT: In the mol-ecule of the title complex, [Ni(C(30)H(29)N(3)O(5))], the Ni atom is coordinated in a distorted square-planar geometry by three N and one O atoms. The aromatic rings are oriented at dihedral angles of 29.01 (3), 79.73 (3) and 83.37 (3)°. The remaining rings adopt envelope conformations with the C and N atoms at the flap positions. In the crystal structure, inter-molecular O-H⋯O hydrogen bonds link the mol-ecules into chains along the b axis. There is also a weak C-H⋯π inter-action.

SUBMITTER: Zhou JD

PROVIDER: S-EPMC2968851 | biostudies-literature | 2009 Mar

REPOSITORIES: biostudies-literature

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(SP-4-4)-[Hydrogen N-({2-[(2S)-1-benzyl-pyrrolidine-2-carboxamido]phen-yl}(phen-yl)methyl-ene)-l-glutamato(2-)]nickel(II).

Zhou Jia-Dong JD Cao Fei F Ying Han-Jie HJ Wei Ping P

Acta crystallographica. Section E, Structure reports online 20090328 Pt 4

In the mol-ecule of the title complex, [Ni(C(30)H(29)N(3)O(5))], the Ni atom is coordinated in a distorted square-planar geometry by three N and one O atoms. The aromatic rings are oriented at dihedral angles of 29.01 (3), 79.73 (3) and 83.37 (3)°. The remaining rings adopt envelope conformations with the C and N atoms at the flap positions. In the crystal structure, inter-molecular O-H⋯O hydrogen bonds link the mol-ecules into chains along the b axis. There is also a weak C-H⋯π inter-action. ...[more]

PMID: 21582389

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