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(4S,5S)-2-(2-Thien-yl)-1,3-dioxolane-4,5-dicarboxamide.

ABSTRACT: In the title compound, C(9)H(10)N(2)O(4)S, which is an important inter-mediate for the preparation of anti-tumor platinum drugs, the dioxolane ring adopts an envelope conformation with the C atom bonded to the thienyl ring at the flap position. Intra-molecular N-H⋯O and C-H⋯O hydrogen bonds result in the formation of two five-membered rings having envelope conformations. In the crystal structure, inter-molecular N-H⋯O and C-H⋯O hydrogen bonds link the mol-ecules into a three-dimensional network.

SUBMITTER: Xu W 

PROVIDER: S-EPMC2968867 | biostudies-literature | 2009 Mar

REPOSITORIES: biostudies-literature

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(4S,5S)-2-(2-Thien-yl)-1,3-dioxolane-4,5-dicarboxamide.

Xu Wei W   Yang Zheng Z   Li Xin-Hua XH   Liu Bo-Nian BN   Wang De-Cai DC  

Acta crystallographica. Section E, Structure reports online 20090314 Pt 4

In the title compound, C(9)H(10)N(2)O(4)S, which is an important inter-mediate for the preparation of anti-tumor platinum drugs, the dioxolane ring adopts an envelope conformation with the C atom bonded to the thienyl ring at the flap position. Intra-molecular N-H⋯O and C-H⋯O hydrogen bonds result in the formation of two five-membered rings having envelope conformations. In the crystal structure, inter-molecular N-H⋯O and C-H⋯O hydrogen bonds link the mol-ecules into a three-dimensional network. ...[more]

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