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Methyl 2-[2-((Z)-{1-trans-[2-(4-fluoro-3-methyl-phen-yl)-2-methyl-cyclo-prop-yl]ethyl-idene}amino-oxymeth-yl)phen-yl]-2-[(E)-methoxy-imino]-acetate.

ABSTRACT: The title compound, C(24)H(27)FN(2)O(4), is an important inter-mediate in the synthesis of fungicidal strobilurin-type compounds. In the crystal structure, the oxime bond attached to the cyclo-propane ring adopts a Z configuration, while the oxime bond attached to the benzene ring adopts an E configuration. The fluoro-methyl-phenyl group adopts a trans configuration with respect to the remainder of the mol-ecule, and its mean plane forms a dihedral angle of 56.1 (1)° with the plane of the cyclo-propane ring.

SUBMITTER: Song C 

PROVIDER: S-EPMC2968980 | biostudies-literature | 2009 Mar

REPOSITORIES: biostudies-literature

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Methyl 2-[2-((Z)-{1-trans-[2-(4-fluoro-3-methyl-phen-yl)-2-methyl-cyclo-prop-yl]ethyl-idene}amino-oxymeth-yl)phen-yl]-2-[(E)-methoxy-imino]-acetate.

Song Chunfeng C   Ross Ronald R   Shaber Steven S   Li Bin B  

Acta crystallographica. Section E, Structure reports online 20090319 Pt 4

The title compound, C(24)H(27)FN(2)O(4), is an important inter-mediate in the synthesis of fungicidal strobilurin-type compounds. In the crystal structure, the oxime bond attached to the cyclo-propane ring adopts a Z configuration, while the oxime bond attached to the benzene ring adopts an E configuration. The fluoro-methyl-phenyl group adopts a trans configuration with respect to the remainder of the mol-ecule, and its mean plane forms a dihedral angle of 56.1 (1)° with the plane of the cyclo-  ...[more]

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