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8-(Biphenyl-2-yl)-7,9-diphenyl-8H-cyclo-penta-[a]acenaphthylen-8-ol.

ABSTRACT: In the title compound, C(39)H(26)O, the cyclo-penta-[a]acenaphthyl-ene skeleton displays the expected distortions, with formal sp(2) bond angles as high as C-C-C = 142.50 (10)°. The OH group forms inter-molecular hydrogen bonds via x-axis translation to the centroid (Cg) of the pendant phenyl ring of the biphenyl system, with H⋯Cg = 2.41 Å and O-H⋯Cg = 153°.

SUBMITTER: Jones PG

PROVIDER: S-EPMC2968992 | biostudies-literature | 2009 Mar

REPOSITORIES: biostudies-literature

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8-(Biphenyl-2-yl)-7,9-diphenyl-8H-cyclo-penta-[a]acenaphthylen-8-ol.

Jones Peter G PG Debeaux Marc M Hopf Henning H Kowalsky Wolfgang W Johannes Hans-Hermann HH

Acta crystallographica. Section E, Structure reports online 20090331 Pt 4

In the title compound, C(39)H(26)O, the cyclo-penta-[a]acenaphthyl-ene skeleton displays the expected distortions, with formal sp(2) bond angles as high as C-C-C = 142.50 (10)°. The OH group forms inter-molecular hydrogen bonds via x-axis translation to the centroid (Cg) of the pendant phenyl ring of the biphenyl system, with H⋯Cg = 2.41 Å and O-H⋯Cg = 153°. ...[more]

PMID: 21582628

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