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{μ-6,6'-Dimeth-oxy-2,2'-[propane-1,3-diylbis(nitrilo-methyl-idyne)]-diphenolato}-trinitratocopper(II)lutetium(III) acetone solvate.

ABSTRACT: In the title complex, [CuLu(C(19)H(20)N(2)O(4))(NO(3))(3)]·CH(3)COCH(3), the Cu(II) ion is four-coordinated in a square-planar geometry by two O atoms and two N atoms from the deprotonated Schiff base. The Lu(III) ion is ten-coordinate, chelated by three nitrate groups and linked to the four O atoms of the deprotonated Schiff base. A mol-ecule of acetone is present as a solvate.

SUBMITTER: Xing JC

PROVIDER: S-EPMC2968995 | biostudies-literature | 2009 Mar

REPOSITORIES: biostudies-literature

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{μ-6,6'-Dimeth-oxy-2,2'-[propane-1,3-diylbis(nitrilo-methyl-idyne)]-diphenolato}-trinitratocopper(II)lutetium(III) acetone solvate.

Xing Jing-Chun JC Xu Yong-Mei YM Cui Xiao-Guang XG Li Wen-Zhi WZ

Acta crystallographica. Section E, Structure reports online 20090325 Pt 4

In the title complex, [CuLu(C(19)H(20)N(2)O(4))(NO(3))(3)]·CH(3)COCH(3), the Cu(II) ion is four-coordinated in a square-planar geometry by two O atoms and two N atoms from the deprotonated Schiff base. The Lu(III) ion is ten-coordinate, chelated by three nitrate groups and linked to the four O atoms of the deprotonated Schiff base. A mol-ecule of acetone is present as a solvate. ...[more]

PMID: 21582380

Similar Datasets

{μ-6,6'-Dimeth-oxy-2,2'-[propane-1,3-diylbis(nitrilo-methyl-idyne)]diphenolato}trinitratocopper(II)erbium(III) acetone solvate.

Project description:In the title complex, [CuEr(C(19)H(20)N(2)O(4))(NO(3))(3)]·CH(3)COCH(3), the Cu(II) ion is coordinated in a square-planar environment by two O atoms and two N atoms of a Schiff base ligand. The Er(III) ion is bis-chelated by three nitrate ligands and coordinated by four O atoms of the Schiff base ligand in a slightly distorted bicapped square-anti-prismatic environment.

| S-EPMC2971433 | biostudies-literature

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Project description:In the title dinuclear Cu(II)-Lu(III) salen-type complex, [CuLu(C(22)H(24)N(2)O(4))(NO(3))(3)], with the ligand 6,6'-dimeth-oxy-2,2'-[cyclo-hexane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolate, the irregular nine-coordinate Lu(III) coordination sphere comprises four O atoms from the ligand and five O atoms from three nitrate groups, two bidentate and one monodentate [Lu-O = 2.230 (3)-2.621 (4) Å]. The slightly distorted square-planar four-coordinate Cu(II) atom comprises two imine N atoms [Cu-N = 1.903 (4) and 1.912 (4) Å] and two phenolate O atoms from the ligand mol-ecule [Cu-O = 1.897 (3) and 1.906 (3) Å]. All atoms of the cyclo-hexane ring of the ligand mol-ecule are disordered over two sets of sites with equal occupancy.

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{?-6,6'-Dimeth-oxy-2,2'-[propane-1,3-diylbis(nitrilo-methyl-idyne)]diphenolato}trinitratocopper(II)europium(III).

Project description:In the title complex, [CuEu(C(19)H(20)N(2)O(4))(NO(3))(3)], the Cu(II) ion is four-coordinated in a square-planar geometry by two O atoms and two N atoms of the deprotonated Schiff base. The Eu(III) atom is ten-coordinate, chelated by three nitrate groups and linked to the four O atoms of the deprotonated Schiff base.

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Project description:In the title complex, [CuNd(C(20)H(22)N(2)O(4))(NO(3))(3)], the Cu(II) ion is coordinated in a distorted square-planar environment by two O atoms and two N atoms of a tetra-dentate Schiff base ligand. The Nd(III) ion is ten-coordinated by three bis-chelating nitrate groups and four O atoms of the Schiff base ligand. The atoms of one of the nitrato ligands are disordered over two sets of sites, with refined occupancies of 0.567 (13) and 0.433 (17).

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{6,6'-Dimeth-oxy-2,2'-[naphthalene-2,3-diylbis(nitrilo-methyl-idyne)]diphenolato}thio-cyanato-cobalt(III) diethyl ether dichloro-methane solvate.

Project description:In the title complex, [Co(C(26)H(20)N(2)O(4))(NCS)]·C(4)H(10)O·CH(2)Cl(2), the penta-coordinated Co(III) atom exhibits a distorted square-pyramidal geometry with an N,N',O,O' tetra-dentate Schiff base ligand in the basal plane and one thio-cyanate ligand at the apical site. The diethyl ether mol-ecule is located in a cavity provided by four O atoms of the ligand with weak C-H?O inter-actions, generating two short O?O contact distances [2.766?(3) and 2.745?(3)?Å] between the diethyl ether mol-ecule and the ligand. The crystal structure is stabilized by the weak C-H?O and C-H?N inter-actions and ?-? inter-actions between the naphthyl ring system and the benzene ring [centroid-centroid distance = 3.657?(5)?Å] and between the two naphthyl ring systems [centroid-centroid distance = 4.305?(2)?Å].

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Aqua{6,6'-dimeth-oxy-2,2'-[propane-1,3-diylbis(nitrilo-methyl-idyne)]diphenolato}copper(II).

Project description:In the asymmetric unit of the title compound, [Cu(C(19)H(20)N(2)O(4))(H(2)O)], there are two independent mononuclear Cu(II) complexes. The coordination environment of each Cu(II) ion is square-pyramidal completed by two N atoms and two O atoms forming the basal plane, and one O atom of the water mol-ecule occupying the apical position. Neighbouring complexes are connected via O-H⋯O hydrogen bonds between the water mol-ecule and the meth-oxy group, forming a chain structure along the a axis. The propyl-ene groups of the two independent complexes are disordered over two positions with site occupancies of 0.361 (7):0.639 (7) and 0.224 (8):0.776 (8). The crystal under investigation was a partial inversion twin.

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Aqua-{6,6'-dimeth-oxy-2,2'-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolato}nickel(II).

Project description:The title complex, [Ni(C(18)H(18)N(2)O(4))(H(2)O)], lies on a mirror plane with the Ni(II) ion coordinated by two N and two O atoms of a tetra-dentate Schiff base ligand and one water O atom in a distorted square-pyramidal enviroment. The -CH(2)-CH(2)- group of the ligand is disordered equally over two sites about the mirror plane. The dihedral angle between the mean planes of the two symmetry-related chelate rings is 37.16 (6)°. In the crystal structure, inter-molecular O-H⋯O hydrogen bonds link complex mol-ecules into one-dimensional chains along [100] and these chains are linked, in turn, by very weak inter-molecular C-H⋯O hydrogen bonds into a two-dimensional network.

| S-EPMC2970327 | biostudies-literature

{μ-6,6'-Dimeth-oxy-2,2'-[butane-1,4-diylbis(nitrilo-methanylyl-idene)]diphenolato}trinitratocopper(II)samarium(III).

Project description:In the monomeric dinuclear title complex, [CuSm(C(20)H(22)N(2)O(4))(NO(3))(3)], the four-coordinate Cu(II) ion has a square-planar geometry involving two O atoms and two N atoms of the deprotonated Schiff base ligand. The Sm(III) ion is ten-coordinate, chelated by four O donor atoms of the Schiff base and two O atoms each from three bidentate nitrate groups, one of which is disordered over two sites in a 0.55 (7):0.45 (7) ratio.

| S-EPMC3200624 | biostudies-literature

Aqua-{6,6-dimeth-oxy-2,2'-[propane-1,3-diylbis(nitrilo-methyl-idyne)]diphenolato-κO,N,N',O'}copper(II) acetonitrile solvate.

Project description:In the title compound, [Cu(C(19)H(20)N(2)O(4))(H(2)O)]·C(2)H(3)N, the Cu(II) ion is coordinated by two N and two O atoms from the tetra-dentate Schiff base ligand, which contains a propyl-ene fragment disordered over two conformations in a 0.64 (1):0.36 (1) ratio, and one O atom from the water mol-ecule in a distorted square-pyramidal geometry. In the crystal structure, inter-molecular O-H⋯O hydrogen bonds link the mol-ecules into chains along the a axis.

| S-EPMC2971939 | biostudies-literature

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