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Bis(ferrocenecarbaldehyde thio-semi-carbazonato-κN,S)zinc.

ABSTRACT: In the title compound, [Fe(2)Zn(C(5)H(5))(2)(C(7)H(7)N(3)S)(2)], the Cp rings of each ferrocene residue have a nearly eclipsed conformation. The two thio-semicarbazone ligands each coordinate the Zn atom in a bidentate mode via the N and S atoms, thereby defining a distorted tetra-hedral environment. N-H⋯S, N-H⋯N, C-H⋯S and C-H⋯N intra- and intermol-ecular inter-actions connect the mol-ecules into a two-dimensional array parallel to (010).

SUBMITTER: Vikneswaran MR

PROVIDER: S-EPMC2969079 | biostudies-literature | 2009 Mar

REPOSITORIES: biostudies-literature

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Bis(ferrocenecarbaldehyde thio-semi-carbazonato-κN,S)zinc.

Vikneswaran M R MR Teoh Siang Guan SG Razak Ibrahim Abdul IA Fun Hoong-Kun HK

Acta crystallographica. Section E, Structure reports online 20090306 Pt 4

In the title compound, [Fe(2)Zn(C(5)H(5))(2)(C(7)H(7)N(3)S)(2)], the Cp rings of each ferrocene residue have a nearly eclipsed conformation. The two thio-semicarbazone ligands each coordinate the Zn atom in a bidentate mode via the N and S atoms, thereby defining a distorted tetra-hedral environment. N-H⋯S, N-H⋯N, C-H⋯S and C-H⋯N intra- and intermol-ecular inter-actions connect the mol-ecules into a two-dimensional array parallel to (010). ...[more]

PMID: 21582327

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