Unknown

Dataset Information

0

Catena-Poly[[(nitrato-κO,O')silver(I)]-μ(3)-4-pyridone-κO:O:O].

ABSTRACT: In the title complex, [Ag(NO(3))(C(5)H(5)NO)](n), the Ag(I) atom is coordinated by two O atoms from two different 4-pyridone ligands and two O atoms from one nitrate anion, displaying a nearly planar coordination geometry. The O atoms of two 4-pyridone ligands bridge two symmetrically related AgNO(3) units, forming a dimer, with an Ag⋯Ag separation of 3.680 (2) Å. Neighbouring dimers are linked into an infinite chain through weak Ag⋯O inter-actions [2.765 (2) Å], Ag⋯Ag inter-actions [3.1511 (4) Å] and π-π stacking inter-actions [centroid-centroid distance = 3.623 (4) Å]. N-H⋯O and C-H⋯O hydrogen bonds assemble these chains into a three-dimensional network.

SUBMITTER: Wu XG 

PROVIDER: S-EPMC2969665 | biostudies-literature | 2009 May

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

catena-Poly[[(nitrato-κO,O')silver(I)]-μ(3)-4-pyridone-κO:O:O].

Wu Xian-Ge XG   Xiao Jun-Xia JX   Qin Liang L  

Acta crystallographica. Section E, Structure reports online 20090529 Pt 6

In the title complex, [Ag(NO(3))(C(5)H(5)NO)](n), the Ag(I) atom is coordinated by two O atoms from two different 4-pyridone ligands and two O atoms from one nitrate anion, displaying a nearly planar coordination geometry. The O atoms of two 4-pyridone ligands bridge two symmetrically related AgNO(3) units, forming a dimer, with an Ag⋯Ag separation of 3.680 (2) Å. Neighbouring dimers are linked into an infinite chain through weak Ag⋯O inter-actions [2.765 (2) Å], Ag⋯Ag inter-actions [3.1511 (4)   ...[more]

Similar Datasets

Unknown catena-Poly[[(nitrato-κO)(1,10-phenanthroline-κN,N')manganese(II)]-μ-nitrato-κO:O'].
| S-EPMC2914918 | biostudies-literature
Unknown catena-[[(nitrato-κO)silver(I)]-μ-1,10-phenanthroline-5,6-dione-κO,O':N,N'].
| S-EPMC3151901 | biostudies-literature
Unknown catena-Poly[[(nitrato-κO,O')silver(I)]-μ-N,N'-bis-(3-pyridyl-methyl-idene)benzene-1,4-diamine].
| S-EPMC3007296 | biostudies-literature
Unknown catena-Poly[[tetra-kis-(hexa-methyl-phospho-ramide-κO)bis-(nitrato-κO,O')yttrium(III)] [silver(I)-di-μ-sulfido-molybdenum(VI)-di-μ-sulfido]].
| S-EPMC3200717 | biostudies-literature
Unknown catena-Poly[[tetra-kis-(hexa-methyl-phospho-ramide-κO)bis-(nitrato-κO,O')samarium(III)] [silver(I)-di-μ-sulfido-tungstate(VI)-di-μ-sulfido]].
| S-EPMC3201561 | biostudies-literature
Unknown catena-Poly[[tetra-kis-(hexa-methyl-phospho-ramide-κO)bis-(nitrato-κO,O')cerium(III)] [silver(I)-di-μ-sulfido-tungstate(VI)-di-μ-sulfido]].
| S-EPMC3011570 | biostudies-literature
Unknown catena-Poly[[tetra-kis-(hexa-methyl-phospho-ramide-κO)bis-(nitrato-κO,O')dysprosium(III)] [molybdenum(VI)-di-μ-sulfido-silver(I)-di-μ-sulfido]].
| S-EPMC3009021 | biostudies-literature
Unknown catena-Poly[[(benzoato-κO,O')(2,2'-bipyridine-κN,N')lead(II)]-μ(3)-nitrato-κO:O,O':O''].
| S-EPMC3011738 | biostudies-literature
Unknown catena-Poly[[[triaqua-(nitrato-κO,O')neodymium(III)]-bis-(μ(2)-pyridinium-4-carboxyl-ato-κO:O')] bis-(perchlorate) monohydrate].
| S-EPMC2968357 | biostudies-literature
Unknown catena-Poly[[tetra-kis-(hexa-methyl-phospho-ramide-κO)bis-(nitrato-κ(2) O,O')erbium(III)] [silver(I)-di-μ-sulfido-tungstate(VI)-di-μ-sulfido]].
| S-EPMC3588238 | biostudies-literature