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(1,10-Phenanthroline-κN,N')(triphenyl-phosphine-κP)silver(I) trifluoro-methane-sulfonate.

ABSTRACT: The structure of the title complex, [Ag(C(12)H(8)N(2))(C(18)H(15)P)]CF(3)SO(3), is based on a distorted trigonal-planar N(2)P coordination of the Ag(I) ion, provided by two N atoms of the bidentate phenanthroline ligand and one P atom of the triphenyl-phosphine ligand. The phenanthroline ligand and one phenyl ring of the triphenyl-phosphine ligand almost lie in one plane (maximum deviation = 0.014 Å from the best planes). The crystal structure may be stabilized by an inter-molecular C-H⋯O hydrogen bond between the phenanthroline ligand and the O atom of the trifluoro-methane-sulfonate anion.

SUBMITTER: Wu JQ 

PROVIDER: S-EPMC2969938 | biostudies-literature | 2009 Aug

REPOSITORIES: biostudies-literature

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(1,10-Phenanthroline-κN,N')(triphenyl-phosphine-κP)silver(I) trifluoro-methane-sulfonate.

Wu Jie-Qiang JQ   Jin Qiong-Hua QH   Hu Ke-Yi KY   Zhang Cun-Lin CL  

Acta crystallographica. Section E, Structure reports online 20090819 Pt 9

The structure of the title complex, [Ag(C(12)H(8)N(2))(C(18)H(15)P)]CF(3)SO(3), is based on a distorted trigonal-planar N(2)P coordination of the Ag(I) ion, provided by two N atoms of the bidentate phenanthroline ligand and one P atom of the triphenyl-phosphine ligand. The phenanthroline ligand and one phenyl ring of the triphenyl-phosphine ligand almost lie in one plane (maximum deviation = 0.014 Å from the best planes). The crystal structure may be stabilized by an inter-molecular C-H⋯O hydrog  ...[more]

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