Difluoridodioxido(1,10-phenanthroline)molybdenum(VI).

ABSTRACT: The title compound, [MoF(2)O(2)(C(12)H(8)N(2))], has non-crystallographic mirror symmetry. The Mo(VI) atom shows a distorted octa-hedral environment, with the phenanthroline N atoms and the two oxide groups forming the equatorial plane and the F atoms occupying the apical positions. Weak C-H⋯O and C-H⋯F hydrogen-bonding contacts and π-π inter-actions [centroid-centroid distance = 3.662 (1) Å] connect the complex mol-ecules into a three-dimensional supra-molecular framework.

SUBMITTER: Wang W 

PROVIDER: S-EPMC2970040 | biostudies-literature | 2009 Aug

REPOSITORIES: biostudies-literature