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(E)-N'-(2-Hydr-oxy-3,5-diiodo-benzyl-idene)-2-nitro-benzohydrazide methanol solvate.

ABSTRACT: In the title compound, C(14)H(9)I(2)N(3)O(4)·CH(3)OH, the Schiff base mol-ecule adopts an E geometry with respect to the C=N bond and the dihedral angle between the benzene rings is 45.0?(2)°; an intra-molecular O-H?N hydrogen bond is present. In the crystal, adjacent Schiff base mol-ecules are linked by methanol solvent mol-ecules through inter-molecular N-H?O and O-H?O hydrogen bonds, forming dimers.

SUBMITTER: Qian HY 

PROVIDER: S-EPMC2970043 | biostudies-literature | 2009 Aug

REPOSITORIES: biostudies-literature

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(E)-N'-(2-Hydr-oxy-3,5-diiodo-benzyl-idene)-2-nitro-benzohydrazide methanol solvate.

Qian Heng-Yu HY   Qu Da-Ping DP  

Acta crystallographica. Section E, Structure reports online 20090826 Pt 9

In the title compound, C(14)H(9)I(2)N(3)O(4)·CH(3)OH, the Schiff base mol-ecule adopts an E geometry with respect to the C=N bond and the dihedral angle between the benzene rings is 45.0 (2)°; an intra-molecular O-H⋯N hydrogen bond is present. In the crystal, adjacent Schiff base mol-ecules are linked by methanol solvent mol-ecules through inter-molecular N-H⋯O and O-H⋯O hydrogen bonds, forming dimers. ...[more]

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