(2-Amino-4,6-dimethyl-pyrimidine-κN)(2-amino-4-methyl-pyrimidine-κN)silver(I) perchlorate.

ABSTRACT: Colourless crystals of the title mixed ligand complex, [Ag(C(5)H(7)N(3))(C(6)H(9)N(3))]ClO(4), were obtained from a solution of 2-amino-4-methyl-pyrimidine, 2-amino-4,6-dimethyl-pyrim-idine and silver perchlorate in water and methanol. The crystal structure is stabilized by inter-molecular N-H⋯O and N-H⋯N hydrogen bonds and π-π stacking inter-actions of the aromatic rings of the two ligands [inter-planar distance = 3.652 (10) Å]. The Ag(I) atom shows a linear coordination [N-Ag-N = 174.6 (1)°].

SUBMITTER: Yang H 

PROVIDER: S-EPMC2970461 | biostudies-literature | 2009 Sep

REPOSITORIES: biostudies-literature