Rietveld refinement of the mixed boracite Fe(1.59)Zn(1.41)B(7)O(13)Br.

ABSTRACT: The structural characterization of the new iron-zinc hepta-borate bromide with composition Fe(1.59)Zn(1.41)B(7)O(13)Br, prepared by chemical transport is reported. A rigid-body model with constrained generalized coordinates was defined in order to hold the positions of the B atoms at reasonable inter-atomic distances that typically would reach unacceptable values because of the weak scattering power of boron. There are three independent sites for the B atoms of which two are tetra-hedrally coordinated. The bond-valence sum around the third B atom, located on a threefold rotation axis, was calculated considering two cases of coordination of boron with oxygens: trigonal-planar and tetrahedral. The contribution of the fourth O atom to the bond-valence sum was found to be only 0.06 v.u., indic

SUBMITTER: Ulloa-Godinez S 

PROVIDER: S-EPMC2971062 | biostudies-literature | 2009 Oct

REPOSITORIES: biostudies-literature