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Aqua-{6,6-dimeth-oxy-2,2'-[propane-1,3-diylbis(nitrilo-methyl-idyne)]diphenolato-κO,N,N',O'}copper(II) acetonitrile solvate.

ABSTRACT: In the title compound, [Cu(C(19)H(20)N(2)O(4))(H(2)O)]·C(2)H(3)N, the Cu(II) ion is coordinated by two N and two O atoms from the tetra-dentate Schiff base ligand, which contains a propyl-ene fragment disordered over two conformations in a 0.64 (1):0.36 (1) ratio, and one O atom from the water mol-ecule in a distorted square-pyramidal geometry. In the crystal structure, inter-molecular O-H⋯O hydrogen bonds link the mol-ecules into chains along the a axis.

SUBMITTER: Wang X

PROVIDER: S-EPMC2971939 | biostudies-literature | 2009 Nov

REPOSITORIES: biostudies-literature

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Aqua-{6,6-dimeth-oxy-2,2'-[propane-1,3-diylbis(nitrilo-methyl-idyne)]diphenolato-κO,N,N',O'}copper(II) acetonitrile solvate.

Wang Xinfang X

Acta crystallographica. Section E, Structure reports online 20091121 Pt 12

In the title compound, [Cu(C(19)H(20)N(2)O(4))(H(2)O)]·C(2)H(3)N, the Cu(II) ion is coordinated by two N and two O atoms from the tetra-dentate Schiff base ligand, which contains a propyl-ene fragment disordered over two conformations in a 0.64 (1):0.36 (1) ratio, and one O atom from the water mol-ecule in a distorted square-pyramidal geometry. In the crystal structure, inter-molecular O-H⋯O hydrogen bonds link the mol-ecules into chains along the a axis. ...[more]

PMID: 21578669

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