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[(Z)-N-(2-Chloro-phen-yl)-O-ethyl-thio-carbamato-κS](triphenyl-phosphine-κP)gold(I).

ABSTRACT: The title compound, [Au(C(9)H(9)ClNOS)(C(18)H(15)P)], features a linear S,P-donor set with a small deviation from the ideal linear geometry due to the proximity of the meth-oxy O atom to Au [Au⋯O = 2.986 (4) Å].

SUBMITTER: Tadbuppa PP

PROVIDER: S-EPMC2971960 | biostudies-literature | 2009 Nov

REPOSITORIES: biostudies-literature

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[(Z)-N-(2-Chloro-phen-yl)-O-ethyl-thio-carbamato-κS](triphenyl-phosphine-κP)gold(I).

Tadbuppa Primjira P PP Tiekink Edward R T ER

Acta crystallographica. Section E, Structure reports online 20091125 Pt 12

The title compound, [Au(C(9)H(9)ClNOS)(C(18)H(15)P)], features a linear S,P-donor set with a small deviation from the ideal linear geometry due to the proximity of the meth-oxy O atom to Au [Au⋯O = 2.986 (4) Å]. ...[more]

PMID: 21578689

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Project description:The title compound, [Au(C(9)H(9)ClNOS)(C(18)H(15)P)], reveals a near linear geometry for the Au atom defined by a S,P-donor set [S-Au-P = 175.86 (3)°]. The deviation from linearity is ascribed to the proximate O atom derived from the thio-carbamato anion [Au⋯O = 2.967 (3) Å].

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[(Z)-O-Ethyl N-(4-chloro-phen-yl)thio-carbamato-κS](triphenyl-phosphine-κP)gold(I) dichloro-methane hemisolvate.

Project description:The Au(I) atom in the title compound, [Au(C(9)H(9)ClNOS)(C(18)H(15)P)]·0.5CH(2)Cl(2), exists within a slightly distorted linear geometry defined by an S,P donor set [S-Au-P angle = 178.01 (4)°]; a close intra-molecular Au⋯O contact [2.964 (4) Å] also occurs. In the crystal structure, mol-ecules are linked into supra-molecular chains propagating along [010] by C-H⋯N, C-H⋯S and C-H⋯π inter-actions. The solvent mol-ecule is disordered about a twofold rotation axis.

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[(Z)-O-Methyl N-(3-chloro-phen-yl)thio-carbamato-κS](triphenyl-phosphine-κP)gold(I).

Project description:The Au atom in the title compound, [Au(C(8)H(7)ClNOS)(C(18)H(15)P)], exists within a slightly distorted linear geometry defined by an S,P-donor set [S-Au-P angle = 174.61 (4)°], with the distortion related to a short intra-molecular Au⋯O contact [2.988 (3) Å]. In the crystal structure, mol-ecules are arranged into supra-molecular chains along the b axis by C-H⋯π inter-actions.

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[(Z)-N-(2-Chloro-phen-yl)-O-methyl-thio-carbamato-κS](triphenyl-phosphine-κP)gold(I).

Project description:In the title compound, [Au(C(8)H(7)ClNOS)(C(18)H(15)P)], the Au(I) atom has a near-linear geometry, defined by an S,P-donor set [S-Au-P = 175.09 (5)°]. The proximity of the meth-oxy O atom to Au may be responsible for the deviation from linearity [Au⋯O = 2.959 (4) Å].

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[(Z)-N-(4-Chloro-phen-yl)-O-methyl-thio-carbamato-κS](triphenyl-phosphine-κP)gold(I).

Project description:The title compound, [Au(C(8)H(7)ClNOS)(C(18)H(15)P)], is characterized by a linear S,P-donor set with a small deviation from the ideal linearity [S-Au-P = 175.14 (5)°] due to the close approach of the O atom to the Au atom [Au⋯O = 2.882 (3) Å]. Loosely associated dimers are formed in the crystal structure through C-H⋯O inter-actions.

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Project description:The title compound, [Au(C(6)H(12)NOS)(C(18)H(15)P)], features a linear S,P-donor set about the central Au atom with a deviation from linearity [S-Au-P = 176.66 (5)°] due to an intra-molecular Au⋯O contact [2.991 (5) Å]. Supra-molecular dimers are formed in the crystal structure mediated by C-H⋯N inter-actions.

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[(Z)-O-Ethyl-N-(o-tol-yl)thio-carbamato-κS](triphenyl-phosphine-κP)gold(I).

Project description:The title compound, [Au(C(10)H(12)NOS)(C(18)H(15)P)], features a linear geometry for the Au atom defined by the S and P donor atoms. A small deviation from the ideal geometry is noted and is ascribed to an intra-molecular Au⋯O contact [2.936 (4) Å]. Inversion dimers are formed in the crystal structure mediated by C-H⋯π inter-actions between centrosymmetrically related o-tolyl residues [C⋯Cg = 3.532 (6) Å].

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[(Z)-O-Ethyl-N-(p-tol-yl)thio-carbamato-κS](triphenyl-phosphine)-κP]gold(I).

Project description:The title compound, [Au(C(10)H(12)NOS)(C(18)H(15)P)], features a linear S,P-donor set about the central Au atom. The thio-carbamate ligand is orientated to place the aryl ring in close proximity to Au [the closest Au⋯C distance is 3.238 (4) Å], which results in a small deviation from the ideal linear P-Au-S geometry.

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[(Z)-O-Ethyl N-(4-nitro-phen-yl)thio-carbamato-κS](triphenyl-phosphine-κP)gold(I) dichloro-methane solvate.

Project description:An S,P-donor set in the title solvate, [Au(C(9)H(9)N(2)O(3)S)(C(18)H(15)P)]·CH(2)Cl(2), defines a linear geometry for the Au(I) atom [S-Au-P = 177.75 (7)°], with the minor distortion ascribed to the influence of an intra-molecular Au⋯O contact [3.019 (6) Å]. In the crystal, the packing is stabilized by a network of C-H⋯S, C-H⋯N and C-H⋯O contacts.

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