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Catena-Poly[[bis-(dimethyl-formamide-κO)cadmium(II)]-di-μ(2)-dicyanamido-κN:N].

ABSTRACT: In the title compound, [Cd(C(2)N(3))(2)(C(3)H(7)NO)(2)], the Cd(2+) ion lies on an inversion center and adopts an octa-hedral coordination geometry, in which four N atoms from four different dicyanamide ligands lie in the equatorial plane and two dimethyl-formamide O atoms occupy the axial positions. The Cd atoms are connected by two dicyanamide ligands, resulting in a neutral chain propagating parallel to [010].

SUBMITTER: Zhang J 

PROVIDER: S-EPMC2972080 | biostudies-literature | 2009 Nov

REPOSITORIES: biostudies-literature

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catena-Poly[[bis-(dimethyl-formamide-κO)cadmium(II)]-di-μ(2)-dicyanamido-κN:N].

Zhang Jinfang J  

Acta crystallographica. Section E, Structure reports online 20091111 Pt 12

In the title compound, [Cd(C(2)N(3))(2)(C(3)H(7)NO)(2)], the Cd(2+) ion lies on an inversion center and adopts an octa-hedral coordination geometry, in which four N atoms from four different dicyanamide ligands lie in the equatorial plane and two dimethyl-formamide O atoms occupy the axial positions. The Cd atoms are connected by two dicyanamide ligands, resulting in a neutral chain propagating parallel to [010]. ...[more]

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