(S)-5-Hexyl-1-[(S)-2-hydr-oxy-1-phenyl-ethyl]-4-meth-oxy-1H-pyrrol-2(5H)-one.

ABSTRACT: The title compound, C(19)H(27)NO(3), was obtained by the reaction of (3S,7aR)-7a-hexyl-7-meth-oxy-3-phenyl-2,3-dihydro-pyrrolo[2,1-b]oxazol-5(7aH)-one and triethyl-silane using titanium(IV) chloride as catalyst. In the mol-ecule, the phenyl and dihydro-pyrrolone rings form a dihedral angle of 83.8 (1)°. O-H⋯O hydrogen-bonding inter-actions lead to the formation of a chain parallel to the a axis.

SUBMITTER: Zheng JF 

PROVIDER: S-EPMC2977772 | biostudies-literature | 2009 Apr

REPOSITORIES: biostudies-literature