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Heptacarbonyl-1κC,2κC-(4-phenyl-pyridine-1κN)di-μ-phenyltellurido-1:2κTe:Te-dirhenium(I).

ABSTRACT: In the title complex, [Re(2)(C(6)H(5)Te)(2)(C(11)H(9)N)(CO)(7)], two Re atoms are coordinated in slightly distorted octa-hedral coordination environments and are bridged by two Te atoms, which are coordinated in trigonal-pyramidal environments. The torsion angle for the Te-Re-Te-Re sequence of atoms is 17.06 (3)°. The crystal structure is stabilized by weak C-H⋯O and C-H⋯π inter-actions. In addition, there are Te⋯Te distances [4.0392 (12) Å] and O⋯O distances [2.902 (19) Å] which are shorter than the sum of the van der Waals radii for these atoms. A short inter-molecular lone pair⋯π distance [C O⋯Cg = 3.31 (2) Å] is also observed.

SUBMITTER: Vanitha A 

PROVIDER: S-EPMC2979103 | biostudies-literature | 2010 Apr

REPOSITORIES: biostudies-literature

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Heptacarbonyl-1κC,2κC-(4-phenyl-pyridine-1κN)di-μ-phenyltellurido-1:2κTe:Te-dirhenium(I).

Vanitha A A   Muthukumaran J J   Krishna R R   Manimaran Bala B  

Acta crystallographica. Section E, Structure reports online 20100414 Pt 5

In the title complex, [Re(2)(C(6)H(5)Te)(2)(C(11)H(9)N)(CO)(7)], two Re atoms are coordinated in slightly distorted octa-hedral coordination environments and are bridged by two Te atoms, which are coordinated in trigonal-pyramidal environments. The torsion angle for the Te-Re-Te-Re sequence of atoms is 17.06 (3)°. The crystal structure is stabilized by weak C-H⋯O and C-H⋯π inter-actions. In addition, there are Te⋯Te distances [4.0392 (12) Å] and O⋯O distances [2.902 (19) Å] which are shorter tha  ...[more]

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